Amino Acid?Induced Interface Charge Engineering Enables Highly Reversible Zn Anode

نویسندگان

چکیده

Despite the impressive merits of low-cost and high-safety electrochemical energy storage for aqueous zinc ion batteries, researchers have long struggled against unresolved issues dendrite growth side reactions metal anodes. Herein, a new strategy zinc-electrolyte interface charge engineering induced by amino acid additives is demonstrated highly reversible plating/stripping. Through electrostatic preferential absorption positively charged arginine molecules on surface anode, self-adaptive established inhibition water adsorption/hydrogen evolution guidance uniform deposition. Consequently, an ultra-long stable cycling up to 2200 h at high current density 5 mA cm?2 achieved under areal capacity 4 mAh cm?2. Even cycled ultra-high 10 cm?2, 900 h-long still demonstrated, demonstrating reliable feature interface. This work provides perspective in realizing bulk anode that can prompt its practical application rechargeable batteries.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2021

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202103514